Abstracts 2001

Abstract of Publication No. 387

Mark Murrie, Helen Stoeckli-Evans and Hans U. Güdel
Assembly of Ni7 and Ni21 Molecular Clusters by Using Citric Acid
Angew. Chem. 113, 2011-2014 (2001)      Full Text (PDF)      DOI-Link     
Angew. Chem. Int. Ed. 40, 1957-1960 (2001)      Full Text (PDF)      DOI-Link     

Abstract: The proligand citric acid has been used to assemble two new anionic NiII clusters, [Ni7(cit)6(H2O)2]10- and [Ni21(cit)12(OH)10(H2O)10]16-, from basic aqueous solution. The former possesses a high-spin S = 7 ground state, while the latter shows predominantly antiferromagnetic exchange.

Last modified: 13.12.11 by Gabriela Frei