Abstract of Publication No. 447
Mark Murrie, Daniel Biner, Helen Stoeckli-Evans and Hans U. Güdel
Increasing the crystallisation temperature to access new spin clusters:
conversion of [Ni8(cit)6(OH)2(H2O)2]10– to
[Ni8(cit)6(OH)2]10–
Chem. Commun. 230-231 (2003)
Abstract:
The role of temperature in the formation of high nuclearity
nickel(II) citrate spin clusters is explored, revealing how
changes in structure and hence magnetic properties can be triggered through
desolvation and ligand reorganisation.
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modified:
13.12.11 by
Gabriela Frei 