Abstracts 2003

Abstract of Publication No. 447

Mark Murrie, Daniel Biner, Helen Stoeckli-Evans and Hans U. Güdel
Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10– to [Ni8(cit)6(OH)2]10–
Chem. Commun. 230-231 (2003)      Full Text (PDF)      DOI-Link     

Abstract: The role of temperature in the formation of high nuclearity nickel(II) citrate spin clusters is explored, revealing how changes in structure and hence magnetic properties can be triggered through desolvation and ligand reorganisation.

Last modified: 13.12.11 by Gabriela Frei