Mikhail Sofin, Hans-Ulrich Güdel, Roland Bircher, Eva-Maria Peters and Martin Jansen
Na10Co4O10, an Oligooxocobaltate(II, III) with Unusual Magnetic Properties
Angew. Chem. 115, 3651-3653 (2003)
Angew. Chem. Int. Ed. 42, 3527-2529 (2003)
Abstract:
(Article without Abstract)
Graphical Abstract:
The novel mixed-valent oligooxocobaltate
can be synthesized through a direct
reaction by the azide/nitrate route. The
magnetic properties of the compound are
characterized by the strongly distinct
hierarchy in the magnetic exchange interactions
within the complex anion (see
picture).