Mark Murrie, Simon J. Teat, Helen Stoeckli-Evans and Hans U. Güdel
Synthesis and Characterization of a Cobalt(II) Single-Molecule Magnet
Angew. Chem. 115, 4801-4804 (2003)
Angew. Chem. Int. Ed. 42, 4653-4656 (2003)
Abstract:
(Article without Abstract)
Graphical Abstract:
Small and attractive: The proligand citric acid has been used to
assemble a new anionic hexanuclear cobalt(II) cluster (see
picture). The complex displays single-molecule magnet (SMM) behavior, with an
energy barrier to the reorientation of magnetization of 26 K, the highest value
to have been recorded for a non-manganese based SMM.