Rachel Shaw, Ian S. Tidmarsh, Rebecca H. Laye, Barbara Breeze, Madeleine Helliwell, Euan K. Brechin, Sarah L. Heath,
Mark Murrie, Stefan Ochsenbein, Hans-Ulrich Güdel and Eric J. L. McInne
Supertetrahedral decametallic Ni(II) clusters directed by m6-tris-alkoxides
Chem. Commun. 1418-1419 (2004)
Abstract:
We report the syntheses, structures and magnetic properties of two decametallic
Ni(II) clusters with unprecedented supertetrahedral
cores, stabilised by the (hitherto unobserved)
m6-coordination modes of the tris-alkoxides
{MeC(CH2O)3}3- and
{C6H9O3}3-.