Roland Bircher, Grégory Chaboussant, Chris Dobe, Hans U. Güdel, Stefan T. Ochsenbein,
Andreas Sieber and Oliver Waldmann
Single-Molecule Magnets Under Pressure
Adv. Funct. Mater. 16, 209-220 (2006)
Abstract:
We feature our recent work in the field of single-molecule magnets (SMMs) using
inelastic neutron scattering (INS). The term "pressure" in the title has
a triple meaning. First, there is the expectation from research-funding agencies
and the public to make some significant steps towards applications. Second, the
synthesis of new compounds and the applications of physical techniques for their
understanding are being pushed to their limits. And third, by applying
hydrostatic pressure, valuable insight into the mechanisms behind the SMM
phenomena can be gained. Examples from our research have been taken to
illustrate these points. After a brief introduction to the technique, the
strength of INS for the accurate determination of exchange and anisotropy
interactions in SMMs is highlighted. We hope to demonstrate that, by pushing INS
measurements to their limits, i.e., using the best available neutron sources and
instrumentation, combined with high quality samples, new insights into the
relevant physical processes in SMMs can be gained.