D. Schaniel, Th. Woike, J. Schefer, V. Petrícek, K. W. Krämer, and H. U. Güdel
Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of
Na2[Fe(CN)5NO]·2D2O
Phys. Rev. B 73, 174108/1-5 (2006)
Abstract:
We report neutron diffraction experiments on the
light-induced metastable state SI in single crystals of
Na2[Fe(CN)5NO]·2D2O. It is shown that the
metastable state SI corresponds to a linkage isomer of the
NO group, the so-called isonitrosyl configuration where the NO ligand
is oxygen bound to the central iron atom.