J. Grimm, J. Fleniken, K. W. Krämer, D. Biner, U. Happek and H. U. Güdel
On the determination of photoionization thresholds of Ce3+ doped
Cs3LuCl6, Cs2LiLuCl6 and
Cs2LiYCl6 by thermoluminescence
J. Lumin. 122-123, 325-328 (2007)
Abstract:
We report on photoionization measurements of three Ce3+ doped
chlorides: Cs3LuCl6, Cs2LiLuCl6 and
Cs2LiYCl6. These chlorides are hygroscopic and must be
kept hermetically sealed in quartz vials, complicating the use of standard
techniques to determine electron transfer processes. Thus, a solely optical
technique, based on thermoluminescence excitation spectroscopy, is applied to
detect the photoionization energies of Ce3+ in the three compounds.