P. Allenspach, A. Furrer,
H. U. Güdel, N. Furer and H. Büttner
Crystal electric field and dimer splitting in Cs3Er2X9
(X = Cl, Br)
Physica B 234-236, 744-745 (1997))
Abstract:
Inelastic neutron scattering technique was used to measure the crystal electric
field (CEF) splitting of Cs3Er2Cl9. Besides a
low lying magnetic excitation at around 2 meV all the other transitions are in
agreement with CEF transitions found in optical measurements. Similar additional
low-lying magnetic transitions were found in
Cs3Er2Br9. While excitations of the rare-earth
dimers most likely play a role, the size of the splitting and its absence in
optical spectra still remain a mystery.